The pursuit of energy efficiency and environmental responsibility in the built environment has driven innovation in architectural design, particularly in window and glazing technologies. Smart windows and advanced sustainable glazing methods are transforming how structures interact with light, heat, and external conditions. These solutions do more than simply let daylight in; they intelligently manage solar gain, thermal performance, and occupant comfort, playing a crucial role in modern sustainable buildings. Below, we explore the advancements, benefits, and future directions of smart windows and sustainable glazing.